Butvar Polyvinyl Butyral Resin Product Types

The different kinds of Butvar resins have their properties laid out in Tables 1 to 5. These resins come in various molecular weights and viscosities. Butvar 76 and Butvar 79 resins have less hydroxyl content compared to other Butvar options, which gives them better solubility.

Generally, when you swap butyral groups for acetate groups, you get a polymer that repels water better and can handle heat more without deforming. This change also boosts the polymer's strength and how well it sticks to different surfaces. The strong sticking power of polyvinyl butyral resins comes from their terpolymer structure. Since each molecule has a choice of three different functional groups on its surface, the likelihood of adhesion to a wide range of substrates is significantly increased.

Although polyvinyl butyral resins (PVB) are generally thermoplastic and soluble in a number of solvents, they can be crosslinked by heat and small amounts of mineral acid.Crosslinking often happens through transacetalization, but it can also be due to more complicated processes, like reactions between acetate or hydroxyl groups on nearby chains.

In practice, crosslinking of polyvinyl butyrals is achieved by reaction with various thermosetting resins such as phenolic, epoxy, urea, dicyanate, and melamine resins. The availability of functional hydroxyl groups in Butvar resins for this type of condensation is an important factor in many applications. Including even a small amount of Butvar resin in thermosetting compositions will significantly improve the strength, flexibility, and adhesion of the cured coating.

Polyvinyl butyral films are known for their great resistance to various substances like aliphatic hydrocarbons and different kinds of oils, except for castor and gypsum oils. They tolerate strong bases, but are sensitive to strong acids. However, when used as components of cured coatings, their resistance to acids, solvents and other chemicals is greatly increased. Butyral withstands temperatures up to 200°F for long periods with little color change.

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